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Notes The authors declare no competing financial interest. References Cook T. Klerke A. Ammonia for hydrogen storage: challenges and opportunities. Schuth F. Ammonia as a possible element in an energy infrastructure: catalysts for ammonia decomposition. Energy Environ. Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting. Molecular Catalysts for Water Oxidation. Whittaker J. Free Radical Catalysis by Galactose Oxidase. Lyons C. Recent advances in phenoxyl radical complexes of salen-type ligands as mixed-valent galactose oxidase models. Science , , Dzik W.

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Ligands that Store and Release Electrons during Catalysis. Lyaskovskyy V. ACS Catal. Luca O. Redox-active ligands in catalysis. Broere D. New avenues for ligand-mediated processes - expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands. ACS Cent. Sengupta D.

Sinha S. Isolation, Characterization, and Catalytic Alcohol Oxidation. Hydrogen Evolution Catalyzed by Cobaloximes. Bhattacharjee A. Estes D. Lacy D. Wilson A. Helm M. Bullock R. Production of hydrogen by electrocatalysis: making the H-H bond by combining protons and hydrides. McNamara W. Cobalt-dithiolene complexes for the photocatalytic and electrocatalytic reduction of protons in aqueous solutions.

Zarkadoulas A. ChemCatChem , 9 , Downes C. Eady S. Solis B. Letko C. Panetier J. Theory Comput. Haddad A. Zhang W. Nickel phlorin intermediate formed by proton-coupled electron transfer in hydrogen evolution mechanism. Dempsey J. Ligand steals spotlight from metal to orchestrate hydrogen production. Thompson E. Sherbow T. Jiang J. For a review on main-group compounds showing transition-metal-like reactivity, see:Power P. Nature , , Gilroy J.

Structural characterization of boratatetrazines and their reduction to borataverdazyl radical anions. Synthesis and characterization of palladium complexes of 3-nitroformazans. Acta , , Transition Metal Complexes of 3-Cyano- and 3-Nitroformazans. Hong S. Formazans and their metal complexes.

Beffa F. Acta , 46 , Dale D. The X-ray crystallographic determination of the structure of di-[3-methyl-1 or 5 -phenyl-5 or 1 -p-tolylformazyl]nickel II. A , Balt S. Electron paramagnetic resonance study of coordination in formazan copper II complexes. Renkema W. Acta Crystallogr. Hey, I. Balcioglu, Y. Chen, D. Stalke, T. Suenobu, S. Fukuzumi, H. Frauendorf, G. Clever, Angew. Coordination Chemistry for Energy Conversion, Catalysis and Nanotechnology The global energy supply and the related environmental issues are the biggest technological challenges because of the increasing world population and the legitimate aspiration of developing countries to reach higher life standards.

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